a) 2Al + 6HCl \(\rightarrow\) 2AlCl₃ + 3H₂

      Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

b) Gọi nAl = x, nFe = y

=> 27x + 56y = 11 (1)

Theo pt: \(\Sigma\)nH₂ = 1,5x + y = \(\dfrac{8,96}{22,4}=0,4mol\)(2)

Từ 1 + 2 => x = 0,2 , y = 0,1

=> mAl = 0,2.27 = 5,4 => %mAl = \(\dfrac{5,4}{11}.100\%\approx49,09\%\)

%mFe = 100 - 49,09 = 50,91%

c) Theo pt: nHCl = 2nH₂ = 0,8 mol

=> mHCl = 0,8 . 36,5 = 29,2g

=> \(m_{dd}\)HCl = 29,2 : 10% = 292g

d) mdd sau phản ứng = m A + mHCl = 11 + 292 = 303g

Theo pt: nAlCl₃ = nAl = 0,2 mol => m AlCl₃ = 26,7g

=> C%AlCl₃ = \(\dfrac{26,7}{303}.100\%\) = 8,81%

tương tự nFeCl₂ = 0,1 mol => C%FeCl₂ = 4,19%

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+3H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ a,n_{HCl}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,8}{8}=0,1\left(l\right)\\ b,FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_2+2AgCl\downarrow\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\\ n_{AgCl}=n_{AgNO_3}=3.n_{AlCl_3}+2.n_{FeCl_2}=3.a+2.b=3.0,2+2.0,1=0,8\left(mol\right)\\ \Rightarrow a=\dfrac{170.0,8}{250}.100=54,4\%\\ b=m_{\downarrow}=m_{AgCl}=0,8.143,5=114,8\left(g\right)\)

Câu 1:

Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)

a) PTHH: Mg + 2 HCl -> MgCl2 + H2

a________2a_______a______a(mol)

MgO +2 HCl -> MgCl2 + H2O

b_____2b_______b___b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

=> mMg=0,2.24=4,8(g)

=>%mMg= (4,8/8,8).100=54,545%

=> %mMgO= 45,455%

b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)

c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)

Câu 2:

Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)

               0,2____0,4_____0,2____0,2   (mol)

           \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                0,2____0,4______0,2____0,2  (mol)

Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)

\(n_{H2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)

        2         6               2             3

        a       0,6             0,2          1,5a

        \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

         1          2              1          1

        b         0,2            0,1              1b

a) Gọi a là số mol của Al

           b là số mol của Fe

\(m_{Al}+m_{Fe}=11\left(g\right)\)

⇒ \(n_{Al}.M_{Al}+n_{Fe}.M_{Fe}=11g\)

 ⇒ 27a + 56b = 11g (1)

Theo phương trình : 1,5a + 1b = 0,4(2)

Từ (1),(2), ta có hệ phương trình : 

            27a + 56b = 0,4

            1,5a + 1b = 0,4

            ⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

 \(m_{Al}=0,2.27=5,4\left(g\right)\)

\(m_{Fe}=0,1.56=5,6\left(g\right)\)

⁰/₀Al = \(\dfrac{5,4.100}{11}=49,09\)⁰/₀

⁰/₀Fe = \(\dfrac{5,6.100}{11}=50,91\)⁰/₀

b) \(n_{HCl\left(tổng\right)}=0,6+0,2=0,8\left(mol\right)\)

\(m_{HCl}=0,8.36,5=29,2\left(g\right)\)

\(m_{ddHCl}=\dfrac{29,2.100}{20}=146\left(g\right)\)

c) \(n_{AlCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)

⇒ \(m_{AlCl3}=0,2.133,5=26,7\left(g\right)\)

\(n_{FeCl2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)

⇒ \(m_{FeCl2}=0,1.127=12,7\left(g\right)\)

\(m_{ddspu}=11+146-\left(0,4.2\right)=156,2\left(g\right)\)

\(C_{AlCl3}=\dfrac{26,7.100}{156,2}=17,09\)⁰/₀

\(C_{FeCl2}=\dfrac{12,7.100}{156,2}=8,13\)⁰/₀

 Chúc bạn học tốt

\(\left\{{}\begin{matrix}Fe\\Al\end{matrix}\right.+HCl->\left\{{}\begin{matrix}FeCl2\\AlCl3\end{matrix}\right.+H2\)

Ta có số mol Fe là x , Al là y (mol)

\(\left\{{}\begin{matrix}56x+27y=11\\127x+133,5y=39,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%mFe=\dfrac{0,1.56}{11}=50,9\%\\\%mAl=\dfrac{0,2.27}{11}=49,09\%\end{matrix}\right.\)

Bảo toàn e :

\(2.nH2=2.nFe+3.nAl\Rightarrow nH2=0,4\left(mol\right)\)

\(V=0,4.22,4=8,96\left(l\right)\)

\(nFe=nFeCl2=0,1\left(mol\right)\)

\(nAl=nAlCl3=0,2\left(mol\right)\)

\(\Rightarrow nHCl\left(pứ\right)=2.0,1+3.0,2=0,8\left(mol\right)\)

\(Cm=\dfrac{n}{V}=\dfrac{0,8}{0,2}=4\left(M\right)\)

\(a,Fe+2HCl\rightarrow FeCl_2+H_2\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\Rightarrow n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\%\approx41,176\%\\ \Rightarrow\%m_{CuO}\approx58,824\%\\ b,n_{CuO}=\dfrac{13,6-0,1.56}{80}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.\left(n_{Fe}+n_{CuO}\right)=2.\left(0,1+0,1\right)=0,4\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)